Events The 1st International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

10.3390/ecsoc-1-02025

This submission belongs to the session a. General Organic Synthesis of the event The 1st International Electronic Conference on Synthetic Organic Chemistry

Published date

01 Sep, 1997

Citation

Yu. I. Smushkevich, I. V. Borodaev, I. V. Aksenova, A. V. Aksenov, Regioselectivity of Arylation of 2,3'-Biquinolyl Dianion, in Proceedings of The 1st International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 1997, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-1-02025

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Regioselectivity of Arylation of 2,3'-Biquinolyl Dianion

A. V. Aksenov ¹

I. V. Aksenova ¹

I. V. Borodaev ¹

Yu. I. Smushkevich ²

1. Stavropol State University, Chair of Organic Chemistry, Stavropol 355009, Russia

2. Russian Mendeleev University of Chemical Technology, Chair of Organic Chemistry, 9 Miusskaya sq., 125047 Moscow, Russia.

Abstract

Dianion of 2,3'-biquinolyl with aryl- and hetaryl halides forms product of arylation to 4'-position, which on treatment with alkyl halides or water yield 1'-alkyl-1',4'dihydro-2,3'-biquinolyls or 4'-aryl-1',4'-dihydro-2,3'-biquinolyls respectively. The oxydation of the latter leads to 4'-aryl-2,3'-biquinolyls. The cation dependence of the arylation is shown.

Keywords

Regioselectivity

arylation

2,3'-biquinolyl dianion

Molecular Ribbons via Diels-Alder Cycloadditions: Synthesis of Models for Solubilized Polyacenes and Polyacene Polyquinones

The Synthesis of (2R,5R)-2-Amino-5-Hydroxyhexanoic Acid by Intermolecular Cycloaddition