Events The 1st International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

10.3390/ecsoc-1-02035

This submission belongs to the session a. General Organic Synthesis of the event The 1st International Electronic Conference on Synthetic Organic Chemistry

Published date

01 Sep, 1997

Citation

Robert Kawecki, Nucleophilic Additions to 10-Isobornylsulfinimines, in Proceedings of The 1st International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 1997, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-1-02035

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Nucleophilic Additions to 10-Isobornylsulfinimines

Robert Kawecki ¹

1. Institute of Organic Chemistry, Polish Academy of Sciences, ul. Kasprzaka 44, 01-224 Warsaw, Poland

Abstract

Optically active sulfinimines proved to be versatile chiral auxiliares in the synthesis of amino-compounds. In this presentation new camphor derived sulfinimine is described, as well as its reactions with some nucleophiles. Lewis acid catalyzed additions of ketene silyl acetal to sulfinimine is presented and hetero Diels-Alder reaction with Brassard's diene. As opposed to majority of sulfur containing chiral auxiliares, title compound may be recycled without loss of optical purity.

Keywords

sulfinimines

sulfinamides

nucleophilic addition

asymmetric synthesis

Diels-Alder reaction.

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