Event submissions
Published
This submission belongs to the session a. General Organic Synthesis of the event The 17th International Electronic Conference on Synthetic Organic Chemistry
Published date
31 Oct, 2013
Citation
Claudio Santi, Caterina Tidei, Luca Sancineto, Luana Bagnoli, Francesca Marini, Claudio Santi, PhSZn-halides: new green thiolates, in Proceedings of The 17th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2013, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-17-a004
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PhSZn-halides: new green thiolates
Claudio Santi 1
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Caterina Tidei 1
Luca Sancineto 1
Luana Bagnoli 1
Francesca Marini 1
Claudio Santi 1
1. Group of Catalysis Synthesis and Organic Green Chemistry (CS-ORG CHEM) - Department of Pharmaceutical Sciences - University of Perugia
Abstract
A new class of bench-stable and odorless zinc thiolates can be prepared by insertion of the elemental zinc into a sulfur-halogen bond. The reulting reagents were used for the regio- and stereoselective thiolysis of epoxides in "on-water" conditions as well as in the solvent free synthesis of thioesters starting from the corresponding acyl halides. A comparison with the reactivity of the selenium analogues will be discussed.This communnication is dedicated to Prof. Lorenzo Testaferri in the occasion of his retirement
Keywords
sulfur
epoxide
acyl chlorides
solvent free
on-water
Manuscript
Santi_text.pdf
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