Events The 17th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 17th International Electronic Conference on Synthetic Organic Chemistry

Published date

31 Oct, 2013

Citation

Lucía Briones-Miguéns, Ana García-Deibe, Matilde Fondo, Jesús Sanmartín-Matalobos, Concepcion González-Bello, A convenient Pd-mediated oxidation of 4-methylbenzyl alcohol, in Proceedings of The 17th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2013, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-17-a012

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A convenient Pd-mediated oxidation of 4-methylbenzyl alcohol

Lucía Briones-Miguéns ¹

Ana García-Deibe ¹

Matilde Fondo ¹

Jesús Sanmartín-Matalobos ¹

Concepcion González-Bello ²

1. Coordination and Supramolecular Chemistry Group (Suprametal), Institute of Materials (iMATUS), Department of Inorganic Chemistry, Faculty of Chemistry, Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, Spain

2. Centro Singular de Investigacion en Química Biológica y Materiales Moleculares (CIQUS), Universidad de Santiago de Compostela, Jenaro de la Fuente s/n, 15782 Santiago de Compostela, Spain.

Abstract

A mild and convenient Pd-mediated aerobic oxidation of 4-methylbenzyl alcohol is described. We have applied the catalytic system Pd(OAc)2/Et3N to the oxidation of 4 methylbenzyl alcohol to 4-methylbenzyaldehyde. This method has resulted effective at room temperature without oxygen or air stream and without activated molecular sieves.

Keywords

Triethylamine/ 4-Methyl benzylalcohol/ Palladium/ 4-Methylbenzaldehyde

Manuscript

jsm3.pdf

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