EventsThe 17th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-17-c004
This submission belongs to the session c. Microwave Assisted Synthesis of the event The 17th International Electronic Conference on Synthetic Organic Chemistry
Published date
31 Oct, 2013
Citation
Claudia D. Della Rosa, Pedro M.E. Mancini, Nitrothiophenes as electrophiles in polar Diels-Alder reactions. Solvent effect and microwave irradiation, in Proceedings of The 17th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2013, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-17-c004
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Nitrothiophenes as electrophiles in polar Diels-Alder reactions. Solvent effect and microwave irradiation

Claudia D. Della Rosa 1
Pedro M.E. Mancini 2
1. Área Química Orgánica- Departamento de Química- Facultad de Ingeniería Química, Universidad Nacional del Litoral. Santiago del Estero 2829. (3000) Santa Fe, Argentina. FAX: +54-342-4571162. *e-mail:pmancini@fiq.unl.edu.ar
2. Laboratorio Fester–IQAL (UNL-CONICET)– Facultad de Ingeniería Química – Santiago del Estero 2829, (3000), Santa Fe, Argentina.
Abstract
In this work the electrophilic behaviour of nitrothiophenes in polar Diels-Alder toward dienes of different nucleophilicity is studied. In thermal conditions the reactions were development in molecular solvents and in protic ionic liquids trying to compare the solvent effects on this class of reactions. In the presence of these solvents the reaction system was exposed to microwave irradiation as a complement of reaction conditions.
Keywords
nitrothiophenes
Diels-Alder
microwave
Manuscript
P.Mancini 2 ECSOC.pdf
Poster
P.Mancini 2 ECSOC.pdf
P.Mancini 2 ECSOC.pdf
Mechanistic Insights into a Zn-Assisted Ring-Chain Tautomerism Process Involving a 1,2,3,4-Tetrahydroquinazoline and a Schiff Base
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