Events The 17th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 17th International Electronic Conference on Synthetic Organic Chemistry

Published date

31 Oct, 2013

Citation

Matilde Fondo, Cristina Portela-Garcia, Jesus Sanmartín-Matalobos, Ana María García-Deibe, Schiff base hydrolysis mediated by d-block metals, in Proceedings of The 17th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2013, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-17-a026

Facebook

Twitter

Schiff base hydrolysis mediated by d-block metals

Matilde Fondo ¹

Cristina Portela-Garcia ¹

Jesus Sanmartín-Matalobos ¹

Ana María García-Deibe ¹

1. Universidad de Santiago de Compostela

Abstract

Condensation of imidazol-2-carboxaldehyde and 2-tosylaminomethylaniline (HLTs) in ethanol under reflux yields the Schiff base H2L. The interaction of this Schiff base with palladium(II), cadmium(II) or zinc(II) acetates in 1:1 molar ratio was investigated. This study demonstrates that the expected Schiff base metal complexes cannot be isolated. Instead, chemical synthesis starting from metal acetates leads to the products Pd(LTs)2.2H2O, Cd(LTs)2 and Zn(LTs)2, as a result of the Schiff base hydrolysis.

Keywords

Schiff base

hydrolysis

zinc

cadmium

palladium

Manuscript

mfondo.pdf

Nitrothiophenes as Electrophiles in Polar Diels-Alder reactions. Solvent Effect and Microwave Irradiation

The Influence of the Methyl Group Position on the Chemical Shifts Values of all Protons in Mono-Methylalkane Molecules in the 1H NMR Spectra