Fiber-to-fiber recycling must be promoted to achieve sustainability in the textile industry. Mixed fiber materials cause significant issues in recycling, making accurate sorting essential for recycling. Garments may contain internal materials called interlinings, which are wrapped in the outer fabric and are not visible from the garment surface. This study proposes a non-destructive method for detecting interlinings in garments using active infrared (IR) thermography. Numerical simulations showed that the presence, thickness, and material of the interlining affected the cooling behavior. Fourier analysis of the surface temperature curves revealed that an increased interlining thickness leads to slower cooling and a greater phase lag, enabling the identification of interlining characteristics from thermal responses.