EventsThe 18th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-18-d001
This submission belongs to the session d. Polymer and Supramolecular Chemistry of the event The 18th International Electronic Conference on Synthetic Organic Chemistry
Published date
31 Oct, 2014
Citation
Rocío Carballido, Rosa Pedrido, Manuel R. Bermejo, Esther Gómez-Fórneas, Marcelino Maneiro, Synthesis and X-ray Crystal Structure of the Thiosemicarbazone L bis(4-N-Methyl-Thiosemicarbazone)-4,4'-Diacetylphenylmethane, in Proceedings of The 18th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2014, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-18-d001
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Synthesis and X-ray Crystal Structure of the Thiosemicarbazone L bis(4-N-Methyl-Thiosemicarbazone)-4,4'-Diacetylphenylmethane

Rocío Carballido 1
Rosa Pedrido 1
Manuel R. Bermejo 1,2
Esther Gómez-Fórneas 3
image
Marcelino Maneiro 3
1. Departamento de Química Inorgánica and Centro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS), Universidade de Santiago de Compostela, Santiago de Compostela, 15782, Spain
2. Departamento de Química Inorgánica and Centro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS), Universidade de Santiago de Compostela
3. Departamento de Química Inorgánica, Facultade de Ciencias, Universidade de Santiago de Compostela, Lugo, 27002, Spain
Abstract
We report herein the synthesis of the tetradentate thiosemicarbazone ligand bis(4-N-methyl-thiosemicarbazone)-4,4'-diacetylphenylmethane, which is a suitable precursor in supramolecular chemistry for the preparation of helical metal complexes. This molecule has been characterized by microanalysis, mass spectrometry, IR and 1H and 13C NMR spectroscopies. Its crystal structure has also been analysed.
Keywords
Thiosemicarbazone
ligand
helical
metal complex
Manuscript
Manuscript_ECSOC18_Rocío Piñeiro.pdf
Poster
Presentation_ECSOC18_Rocío Piñeiro.pdf
Presentation_ECSOC18_Rocío Piñeiro.pdf
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