EventsThe 18th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-18-e005
This submission belongs to the session e. Computational Chemistry of the event The 18th International Electronic Conference on Synthetic Organic Chemistry
Published date
31 Oct, 2014
Citation
Jesús Sanmartín-Matalobos, Cristina Portela-García, Matilde Fondo, Ana García-Deibe, Different Bridging Preferences of Zinc and Palladium in Dimeric Complexes of a Ligand Based on 2-Tosylaminomethylaniline, in Proceedings of The 18th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2014, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-18-e005
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Different Bridging Preferences of Zinc and Palladium in Dimeric Complexes of a Ligand Based on 2-Tosylaminomethylaniline

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Jesús Sanmartín-Matalobos 1
Cristina Portela-García 1
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Matilde Fondo 1
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Ana García-Deibe 1
1. Coordination and Supramolecular Chemistry Group (Suprametal), Institute of Materials (iMATUS), Department of Inorganic Chemistry, Faculty of Chemistry, Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, Spain
Abstract
We report here the formation of dimeric palladium(II) and zinc(II) complexes of a ligand (H2L) derived from the condensation of 2 tosylaminomethylaniline and 2,3-dihydroxybenzaldehyde.The structures in solution of the corresponding palladium(II) and zinc(II) complexes could be deduced from NMR studies. With the aim of establishing an energy-structure relationship between the two possible linkage isomers (μ-O bridged and μ-N bridged), some theoretical energy calculations have been performed.
Keywords
Linkage isomerism
dimeric complexes
sulfonamido bridge
phenoxo bridge
Manuscript
Proceeding JSM_linkage.pdf
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