This submission belongs to the session a. General Organic Synthesis of the event The 18th International Electronic Conference on Synthetic Organic Chemistry
Published date
31 Oct, 2014
Citation
Jesús Sanmartín-Matalobos, Ana García-Deibe, Matilde Fondo, José Luis Pérez-Lustres, Sourav Sourav Bhowmick, Neeladri Das, Synthesis and Characterization of a New Triptycene-Based Tripod, in Proceedings of The 18th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2014, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-18-a007
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Synthesis and Characterization of a New Triptycene-Based Tripod
Jesús Sanmartín-Matalobos 1
Ana García-Deibe 1
Matilde Fondo 1
José Luis Pérez-Lustres 2
Sourav Sourav Bhowmick 3
Neeladri Das 3
1. Coordination and Supramolecular Chemistry Group (Suprametal), Institute of Materials (iMATUS), Department of Inorganic Chemistry, Faculty of Chemistry, Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, Spain
2. Centro Singular de Investigacion en Química Biológica y Materiales Moleculares (CIQUS), Universidad de Santiago de Compostela, Jenaro de la Fuente s/n, 15782 Santiago de Compostela, Spain.
3. Department of Chemistry. Indian Institute of Technology (IIT) of Patna. Patna, Bihar, 800013. INDIA
Abstract
Herein, we report an efficient and facile synthesis of a new triptycene based tripodal ligand containing both imine functionality and phenolic pendant arms. This tripodal unit is a potential building block for constructing novel supramolecular architectures. The newly synthesized 2,6,14-triaminotriptycene derivative, which was characterized by FT-IR, UV−Vis absorption, mass and NMR spectroscopic techniques has interesting properties such as high solubility in common organic solvents and fluorescence emission in THF solution (λ = 550 nm).
Keywords
Fluorescence emission
Triptycene derivatives
Schiff bases
Tripods
Manuscript
Proceeding JSM triaminotriptycene.pdf
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