Events The 18th International Electronic Conference on Synthetic Organic Chemistry

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Published

This submission belongs to the session d. Polymer and Supramolecular Chemistry of the event The 18th International Electronic Conference on Synthetic Organic Chemistry

Published date

31 Oct, 2014

Citation

Nikolay Kryukov, Dmitriy Fomichev, Dmitriy Ovsyannikov, Sergei Zelentsov, Polymerisation Kinetics Photoinduced by Derivatives of Para-Nitroaniline in the Presence of N,N-Dipropylaniline, in Proceedings of The 18th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2014, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-18-d006

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Polymerisation Kinetics Photoinduced by Derivatives of Para-Nitroaniline in the Presence of N,N-Dipropylaniline

Nikolay Kryukov ¹

Dmitriy Fomichev ¹

Dmitriy Ovsyannikov ¹

Sergei Zelentsov ¹

1. Lobachevsky State University of Nizhni Novgorod

Abstract

We investigated a possibility of the para-nitroaniline applying as a photopolymerization initiator. To carry out photopolymerization a system consisting of para-nitroaniline and N,N-Dipropylaniline was irradiated with UV light with a wavelength at 365 nm. When adding monomer in this system there was observed polymer formation. It is important to note that these results were not detected using either the nitro compound or the amine monomer as well as to the system without the monomer. The paper shows the kinetics of polymerization at low conversion with different ratios of amine and nitro compounds.

Keywords

Photopolymerization initiator

para-nitroaniline

N,N-Dipropylaniline

Manuscript

Full Paper.pdf

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