Events The 18th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 18th International Electronic Conference on Synthetic Organic Chemistry

Published date

31 Oct, 2014

Citation

Matilde Fondo, Jesús Doejo, Ana María García-Deibe, Jesus Sanmartín-Matalobos, Concepción González-Bello, Total Hydrolysis of a New Imidazolidine Induced by ZnII, in Proceedings of The 18th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2014, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-18-a026

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Total Hydrolysis of a New Imidazolidine Induced by ZnII

Matilde Fondo ¹

Jesús Doejo ¹

Ana María García-Deibe ¹

Jesus Sanmartín-Matalobos ¹

Concepción González-Bello ¹

1. Universidad de Santiago de Compostela

Abstract

2,2´-(2-(2-hydroxyphenyl)imidazolidin-1,3-diyl)diethanol(H3L) was obtained by condensation between 2-hydroxybenzaldehyde and N,N'-bis(2-hydroxyethyl)ethylenediamine. Its potential ability as NNOOO donor towards ZnII was tested. This study shows that zinc(II) mediates the fast hydrolysis of H3L, yielding the free aldehyde and amine. This latter was crystallographically characterised, showing a supramolecular 1D architecture based on hydrogen bond interactions.

Keywords

Imidazolidine

hydrolysis

zinc

1D ladder

Manuscript

mfondo.pdf

The Mechanism of the Photochemical Oxidation of Substrates of Different Nature by Nitro Compounds

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