Events The 13th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session f. Polymer and Supramolecular Chemistry of the event The 13th International Electronic Conference on Synthetic Organic Chemistry

Published date

05 Nov, 2009

Citation

José Vázquez Tato, Luciano Galantini, Francisco Meijide, Aida Jover, Mercedes Alvarez Alcalde, Alvaro Antelo, Complexation of adamantyl derivatives by a β–cyclodextrin dimer., in Proceedings of The 13th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2009, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-13-00258

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Complexation of adamantyl derivatives by a β–cyclodextrin dimer.

José Vázquez Tato ¹

Luciano Galantini ²

Francisco Meijide ¹

Aida Jover ¹

Mercedes Alvarez Alcalde ¹

Alvaro Antelo ¹

1. Departamento de Química Física, Facultad de Ciencias, Universidad de Santiago de Compostela, Avda. Alfonso X El Sabio s/n, 27002 Lugo, Spain

2. Dipartimento di Chimica, Research center SOFT-INFM-CNR, Università di Roma “La Sapienza”, P.le A. Moro 5, 00185 Roma, Italy

Abstract

The binding constants, standard molar enthalpy, Gibbs free energy, and entropy changes were determined for the formation of complexes between adamantyl derivatives and a β-cyclodextrin dimer. It is concluded that, within experimental error, the two cyclodextrin residues in the dimer behave independent to each other when complexing the adamantyl derivatives.

Keywords

Theoretical calculations on conformations of bile-acid based dimers. Interactions with ibuprofen

Complexation of 3α,7α,12α-trihydroxy-5β-cholan-24-amine by β- and γ-cyclodextrins