Events The 18th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session d. Polymer and Supramolecular Chemistry of the event The 18th International Electronic Conference on Synthetic Organic Chemistry

Published date

03 Nov, 2014

Citation

Ana García-Deibe, Cristina Portela-García, Matilde Fondo, Jesús Sanmartín-Matalobos, H-Bonded Polymerisation of Alternate Δ and Λ Metallohelicates, in Proceedings of The 18th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2014, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-18-d011

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H-Bonded Polymerisation of Alternate Δ and Λ Metallohelicates

Ana García-Deibe ¹

Cristina Portela-García ¹

Matilde Fondo ¹

Jesús Sanmartín-Matalobos ¹

1. Coordination and Supramolecular Chemistry Group (Suprametal), Institute of Materials (iMATUS), Department of Inorganic Chemistry, Faculty of Chemistry, Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, Spain

Abstract

The neutral cadmium(II) complex Cd(HL)2 (H2L = 2-[(1H-imidazol-2-yl)methyleneamino]phenol) is chiral and it can be considered as a simple metallohelicate, with its corresponding Δ and Λ enantiomers. In the solid state, its helixes are hierarchically assembled as a linear polymer, via mutual N-H···O interactions between each two alternating enantiomers, and which also are π-π stacked, so this polymer is based on a by a dimeric repeat unit {Δ,Λ-[Cd(HL)2]2}.

Keywords

Chirality

H-bond

polymer

metallohelicate

self-assembly

Manuscript

Proceeding AGD polymer.pdf

Preparation of Activated Carbon with High Surface Area from Pistacia Aatlantica Shell

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