EventsThe 18th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-18-a045
This submission belongs to the session a. General Organic Synthesis of the event The 18th International Electronic Conference on Synthetic Organic Chemistry
Published date
03 Nov, 2014
Citation
Hasnaa Sadeq, Thies Thiemann, John P Graham, Yosef Al Jasem, Bernhard Bugenhagen, Nathir al Rawashdeh, Extended Anthracenes and Their Use as Dienes in Diels-Alder Reactions, in Proceedings of The 18th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2014, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-18-a045
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Extended Anthracenes and Their Use as Dienes in Diels-Alder Reactions

Hasnaa Sadeq 1
Thies Thiemann 2
John P Graham 1
Yosef Al Jasem 3
Bernhard Bugenhagen 4
Nathir al Rawashdeh 5
1. Department of Chemistry, UAE University
2. Department of Chemistry, United Arab Emirates University
3. Department of Chemical Engineering, UAE University
4. Institute of Inorganic Chemistry, University of Hamburg
5. Department of Applied Chemical Sciences, Jordan University of Science & Technology
Abstract
9-Anthranylcarbaldehydes were converted to alkyl 9-anthranylacrylates and 9-phenacylethenylanthracenes. Alkyl 9-anthranylacrylates are brominated to alkyl 9-bromoanthran-10-ylacrylate. Suzuki-reactions with arylboronic lead to alkyl 9,10-arylanthranylacrylates. The alkyl 9-anthranylacrylates and 9-phenacylethenylanthracenes were subjected to cycloaddition reactions to give the respective cycloadducts.
Keywords
Anthracenes
Wittig-olefination
Suzuki reaction
Diels Alder reaction
extended pi-systems
photochemistry
Manuscript
Extended-anthracenes-Thiemann.pdf
Poster
ECSOC-Presentation1.pdf
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