This submission belongs to the session a. General Organic Synthesis of the event The 19th International Electronic Conference on Synthetic Organic Chemistry
Published date
30 Oct, 2015
Citation
Mariam Al Azani, Nuha al Soom, Jesus Iniesta, Thies Thiemann, Thies Thiemann, Facile access to amidoethyl-p-benzoquinones, in Proceedings of The 19th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2015, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-19-a035
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Facile access to amidoethyl-p-benzoquinones
Mariam Al Azani 1
Nuha al Soom 1
Jesus Iniesta 2
Thies Thiemann 1
Thies Thiemann 1
1. Department of Chemistry, United Arab Emirates University, Al Ain, UAE
2. Institute of Electrochemistry and Physical Chemistry Department, University of Alicante
Abstract
Amidoethyl-p-benzoquinones are easily accessible from 2,5-dimethoxybenzaldehyde. A one-step Wittig-hydrolysis reaction is followed by an amidation of the produced 2,5-dimethoxycinnamic acid. Hydrogenation and oxidative demethylation complete the sequence to the respective amidoethyl-p-benzoquinones. The spectroscopic data of the products is discussed.
Keywords
p-benzoquinones
oxidative demethylation
amides
Manuscript
Facile access to amidoethyl.pdf
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