Events The 19th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 19th International Electronic Conference on Synthetic Organic Chemistry

Published date

30 Oct, 2015

Citation

Victor Fabricio Terraza, Darío César Gerbino, Julio César Podestá, Synthesis and some properties of mixed alkyl(-)menthyltin dihydrides, in Proceedings of The 19th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2015, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-19-a043

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Synthesis and some properties of mixed alkyl(-)menthyltin dihydrides

Victor Fabricio Terraza ¹

Darío César Gerbino ²

Julio César Podestá ²

1. Instituto de Química del Sur (INQUISUR), Departamento de Química, Universidad Nacional del Sur-CONICET, Av. Alem 1253, 8000, Bahía Blanca, Argentina. CIC-PBA, Argentina

2. Instituto de Química del Sur (INQUISUR), Departamento de Química, Universidad Nacional del Sur-CONICET, Av. Alem 1253, 8000, Bahía Blanca, Argentina

Abstract

This communication reports the synthesis of a series of new (-)menthylalkyltin dihydrides of type (-)MenRSnH2 (R = Me, i-Pr, n-Bu, and t-Bu), starting from the known (-)MenMe2SnBr (1). These organotin dihydrides containing a bulky chiral (-)menthyl substituent and alkyl groups of increasing steric volume should be of interest in the reduction of prochiral ketones and unsaturated systems. Physical characteristics of the new diorganotin hydrides and some of their precursors including selected values1H, 13C, and 119Sn NMR data are given.

Keywords

(-)Menthylalkyltin dihydrides - synthesis - physical properties

Manuscript

Synthesis and some properties of mixed alkyl.pdf

Poster

Synthesis and some properties of mixed alkyl.pdf

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