EventsThe 19th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-19-d004
This submission belongs to the session d. Polymer and Supramolecular Chemistry of the event The 19th International Electronic Conference on Synthetic Organic Chemistry
Published date
30 Oct, 2015
Citation
Julio A. Seijas, Eva Carolina Vázquez Barreiro, José Vázquez Tato, Francisco José Fraga López, Aida Jover Ramos, Study of the crosslinking reaction between Bisphenol A diglycidyl ether (BADGE) and a Zinc Porphyrin by Fourier transform infrared spectroscopy., in Proceedings of The 19th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2015, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-19-d004
Share
Email
Facebook
Twitter
LinkedIn

Study of the crosslinking reaction between Bisphenol A diglycidyl ether (BADGE) and a Zinc Porphyrin by Fourier transform infrared spectroscopy.

Eva Carolina Vázquez Barreiro 1
Aida Jover Ramos 2
image
Francisco José Fraga López 1
José Vázquez Tato 2
image
Julio A. Seijas 3
1. Departamento de Física Aplicada. Facultad de Ciencias. Universidad de Santiago de Compostela. Campus Lugo. 27080-Lugo. Spain
2. Departamento de Química Física. Facultad de Ciencias. Universidad de Santiago de Compostela. Campus Lugo. 27080-Lugo. Spain
3. Departamento de Química Orgánica. Facultad de Ciencias. Universidad de Santiago de Compostela. Campus Lugo. 27080-Lugo. Spain
Abstract

The curing reaction of a system consisting of a diglycidyl ether of bisphenol-A (n= 0) and ZnTPyP (Zinc 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphyrin) was studied by Fourier Transform infrared spectroscopy (FTIR). A semi-empirical quantum chemistry program (MOPAC) was used to corroborate the experimental data. The tertiary amine ZnTPyP not only initiates the reaction but also reacts with the resin forming pyridone. This study demonstrates that macrocycles can be used as cross-linking agents for curing epoxy resins and that when metallomacrocycles are used, metal ions can be introduced into the network structure.

Keywords
FTIR
porphyrins
epoxy resins
tertiary amines
Manuscript
Study of the Crosslinking reaction.pdf
Recognition of transition metals by benzimidazoles with an optical response
Synthesis of tailored Aromatic quaternized Chitosan probes as switchable redox devices