EventsMOL2NET'16, Conference on Molecular, Biomed., Comput. & Network Science and Engineering, 2nd ed.
Event submissions
Published
with-doi10.3390/MOL2NET-02-H010
This submission belongs to the session 02. CHEMBIOMOL-02: Chem. Biol. & Med. Chem. Workshop, Rostock, Germany-Bilbao, Spain-Galveston, Texas, USA, 2016 of the event MOL2NET'16, Conference on Molecular, Biomed., Comput. & Network Science and Engineering, 2nd ed.
Published date
22 May, 2016
Citation
Esther Domínguez, Garazi Urgoitia, María Teresa Herrero, Raul SanMartin, New catalytic systems for oxygen-mediated oxidative processes, in Proceedings of MOL2NET'16, Conference on Molecular, Biomed., Comput. & Network Science and Engineering, 2nd ed., 15 October–20 October 2022, MDPI: Basel, Switzerland, doi: 10.3390/MOL2NET-02-H010
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New catalytic systems for oxygen-mediated oxidative processes

Garazi Urgoitia 1
image
Raul SanMartin 1
María Teresa Herrero 1
Esther Domínguez 1
1. Department of Organic Chemistry II, University of the Basque Country UPV/EHU, 48940, Bilbao, Spain.
Abstract

The oxidation of alcohols to the corresponding carbonyl compounds is a current transformation in laboratory and industrial chemistry. Traditionally this reaction involves oxidants used in stoichiometric or overstoichiometric amounts so that relatively large quantities of waste are generated. Molecular oxygen is the ideal oxidant (readily available, safe, environmentally friendly, water as waste, etc.), but the need of metal catalysts to control the reaction outcome in relatively high amounts can become a serious drawback.[1],[2] We wish to present two pallacyclic systems with remarkable catalytic properties in the aerobic oxidation of a number of alcohols.

[1] Sheldon, R.A.; Arends, I.W.C.E.; ten Brink, G.J.; Dijksman, A. Acc. Chem. Res. 2002, 35, 774-778.

[2] Verho, O., Dilenstam, M.D.V.; Kärkäs, M.D., Johnston, E.V.; Åkermark, T.; Bäckvall, J.E.; Åkermark, B. Chem. Eur. J. 2012, 18, 16947-16954.

Keywords
catalysis
oxidative processes
alcohols
oxygen
Manuscript
SL5. Garazi Urgoitia.pdf
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