Synthesis, Identification and Application Studies of a Cu(II) Complex with1,1’,((1E,1’E)-1,2-phenylene bis (diazene-2,1-diyl))bis(naphthalen-2-ol)

The Schiff base ligands and their corresponding metal complexes have expanded enormously and include a vast area of organometallic compounds and various aspects of bioinorganic chemistry [1]. On the other hand, azo compounds are very important molecules and have attracted much attention in both academic and applied research [2]. The azo compounds and their metal-azo complexes are extremely used in dyes and data storage [3]. In this paper, a new complex of Cu(II) and the title Schiff base as a ligand is reported. Elemental, and spectroscopic measurements are used to elucidate the structure of the prepared metal complex. The azo-dye Schiff base behaves as a di-negative N₂O₂ tetradentate ligand. The structure of metal complex is square planar. The azo-dye Schiff base and its complex is characterized by FTIR, DRS, EDAX and thermal analysis methods. 

References

[1] T.T. Tidwell, Angew Chem. Int. Ed. 47 (2008) 1016–1020. 

[2] H. Nishihara, Bull. Chem. Soc. Japan 77 (2004) 407–428. 

[3] R. Asgari-sabet, H. Khoshsima, Dyes Pigm. 87 (2010) 95–99.