EventsThe 20th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-20-a041
This submission belongs to the session a. General Organic Synthesis of the event The 20th International Electronic Conference on Synthetic Organic Chemistry
Published date
01 Nov, 2016
Citation
Francisco Reigosa Chamorro, Fátima Lucio, Adolfo Fernández-Figueiras, Paula Munín, José Manuel Vila, María Teresa Pereira, Pablo Frieiro, Functionalized thiosemicarbazone ligands and their complexes., in Proceedings of The 20th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2016, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-20-a041
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Functionalized thiosemicarbazone ligands and their complexes.

Francisco Reigosa Chamorro 1
Fátima Lucio 1
Adolfo Fernández-Figueiras 1
Paula Munín 1
José Manuel Vila 1
María Teresa Pereira 1
Pablo Frieiro 1
1. University of Santiago de Compostela, Department of Inorganic Chemistry
Abstract

The purpose of this work is the design, synthesis and characterization of thiosemicarbazone ligands bearing a phenyl boronic acid functionality. The main interest is the synthesis of organopalladium compounds with the boronic acid included within the corresponding molecule. These could lead to further modification of the properties of the organometallic species applicable to the Suzuki-Miyaura reaction.

The ligands were prepared by reaction of acetylphenylboronic acid with several thiosemicarbazides. The compounds were characterized by IR, 1H and 31P NMR spectroscopy.

References:

Adrio, L.A., PhD Dissertation, University of Santiago de Compostela, 2006.

Bermúdez, B., PhD Dissertation, University of Santiago de Compostela, 2014.

Acknowledgments 

We wish to thank the financial support received from the Xunta de Galicia (Galicia, Spain) under the Grupos de Referencia Competitiva Programme Projects GRC2015/009.

Keywords
Boronic Acid
Catalysis
Suzuki
Thiosemicarbazone
Ligand
Metal
Characterization,
Manuscript
Fullpaper FRC.pdf
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