Adverse childhood experiences (ACEs) may constitute a risk factor for the development of secure attachment and healthy psychological adjustment in adolescence. The aim of this study was to analyse the relationship between ACEs and the variables of attachment, dissociation, behavioural problems and psychopathy. To this end, standardised self-assessment questionnaires were administered to a sample of n = 108 adolescents aged between 14 and 18 (64.8 percent female and 35.2 percent male), and Pearson’s correlations were calculated. It was found that greater exposure to ACEs during childhood was positively and significantly associated with: anxiety, avoidance and anger in attachment; with all dimensions of dissociation (in particular, depersonalisation); with increased symptoms of hyperactivity; with behavioural problems; emotional symptoms and difficulties in peer relationships; and psychopathic traits (in particular, egocentrism). Furthermore, a significant negative correlation was observed with the factors of emotional competence and prosocial behaviour. Based on these findings, it was concluded that adverse childhood experiences could have a significant influence on the emotional and behavioural development of children and adolescents. Consequently, emphasis was placed on the importance of implementing preventive approaches and early, comprehensive interventions, taking into account the influence of the family environment and other contexts relevant to children that could act as protective factors.