Events The 14th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 14th International Electronic Conference on Synthetic Organic Chemistry

Published date

22 Oct, 2010

Citation

Sergey Vasylievitch Zelentsov, Dmitriy Vladimirovitch Katin, SYNTHESIS AND PHOTOCHEMICAL PROPERTIES OF POLYOXOMETALATES CONTAINING para – NITROBENZENE PHOSPHOROUS ACID FRAGMENT, in Proceedings of The 14th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2010, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-14-00387

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SYNTHESIS AND PHOTOCHEMICAL PROPERTIES OF POLYOXOMETALATES CONTAINING para – NITROBENZENE PHOSPHOROUS ACID FRAGMENT

Sergey Vasylievitch Zelentsov ¹

Dmitriy Vladimirovitch Katin ¹

1. SYNTHESIS AND PHOTOCHEMICAL PROPERTIES OF POLYOXOMETALATES CONTAINING para – NITROBENZENE PHOSPHOROUS ACID FRAGMENT

Abstract

We synthesized a new hybrid organo-inorganic polyoxometalate from Na₂WO₄ and di-sodium salt of para-nitrophenyl ester of phosphoric acid, Na₂C₆H₄NO₂@[PW₁₂O₄₀]. Photochemical activity of the compound towards mandelic acid and isopropyl alcohol was studied. It was shown that the polyoxometalate synthesized behaves itself as a powerful photooxidazing agent and/or a catalyst of the photochemical oxidation of the said H-atom donors by nitrocompound in the presence of oxygen.

Keywords

hybrid polyoxometalate

synthesis

para-nitrophenyl ester of phosphoric acid

photochemical oxidation

catalytic activity

Mesomorphic properties of new cholesteryl derivatives

The theoretical study of bisphosphonate derivatives as drug for inhibition of cancer