Events The 14th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 14th International Electronic Conference on Synthetic Organic Chemistry

Published date

31 Oct, 2010

Citation

Hadi Amiri Rudbari, Giuseppe Bruno, A. Taeb, A. Kakanejadi, Reza Azadbakht, Saeed Menati, Synthesis and characterization of three new asymmetric Schiff bases and X-ray crystal structure of [H 2 cd3-OMesalen] ligand, in Proceedings of The 14th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2010, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-14-00432

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Synthesis and characterization of three new asymmetric Schiff bases and X-ray crystal structure of [H 2 cd3-OMesalen] ligand

Hadi Amiri Rudbari ¹

Giuseppe Bruno ¹

A. Taeb ²

A. Kakanejadi ³

Reza Azadbakht ⁴

Saeed Menati ⁵

1. Dipartimento di Chimica Inorganica, Vill. S. Agata, Salita Sperone 31, Universita di Messina, 98166 Messina, Italy

2. Department of Chemistry,Science and Research Branch, Islamic Azad University, Tehran, Iran

3. Department of Chemistry, University of Lorestan, Lorestan, Iran

4. Department of chemistry, Payame Noor University, Hamedan, Iran

5. Department of Chemistry, Islamic Azad University, Khorramabad, Iran.

Abstract

Three new asymmetric Schiff base compounds, (E)-methyl 2-(2-(2-hydroxy-3-methoxybenzylideneamino)ethylamino)cyclopent-1-enecarbodithioate[H 2 cd3-OMesalen](1), (E)-methyl 2-(2-(3,5-di-tert-butyl-2-hydroxybenzylideneamino)ethylamino)cyclopent-1-enecarbodithioate[H 2 cd di tertbutsalen] (2) and (E)-methyl2-(2-(3-hydroxy-4-methoxybenzylideneamino)ethylamino)cyclopent-1-enecarbodithioate[H 2 cd4-OMesalen] (3) have been prepared. The compounds have been studied with IR, 1 H NMR, 13 C NMR and microanalysis. The crystal structure of (1) has been also determined.

Keywords

Schiff base

asymmetric compounds

crystal structure

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