EventsThe 14th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-14-00437
This submission belongs to the session a. General Organic Synthesis of the event The 14th International Electronic Conference on Synthetic Organic Chemistry
Published date
25 Oct, 2010
Citation
M. J. Rodríguez-Doutón, M. Maneiro, A. M. González-Noya, B. Fernández, M. I. Fernández, M. A. Vázquez- Fernández, SYNTHESIS OF DICOMPARTIMENTAL SCHIFF BASE LIGANDS. CRYSTAL STRUCTURE OF (N-N'-BIS(3- METHOXY or 3-ETHOXYSALICYLIDENE)-1,2-DIAMINE-2-METHYLPROPANE, in Proceedings of The 14th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2010, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-14-00437
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SYNTHESIS OF DICOMPARTIMENTAL SCHIFF BASE LIGANDS. CRYSTAL STRUCTURE OF (N-N'-BIS(3- METHOXY or 3-ETHOXYSALICYLIDENE)-1,2-DIAMINE-2-METHYLPROPANE

M. J. Rodríguez-Doutón 1
M. Maneiro 1
A. M. González-Noya 1
B. Fernández 1
M. I. Fernández 1
M. A. Vázquez- Fernández 1
1. Dpto. de Química Inorgánica. Facultad de Ciencias. Univ. de Santiago de Compostela. 27002 Lugo (Spain).
Abstract
The condensation of 3-methoxy or 3-ethoxy-2-hydroxybenzaldehyde and 1,2 diamine -2-methylpropane, to yield at the dianionic hexadentate Schiff base ligands H2 Ln (H2 L1 , H2 L2 respectively). The ligands have been characterised by elemental analysis, IR, 1H and 13C NMR spectroscopies and mass spectrometry (ES). The crystal structure of the two ligands was solved by X-ray crystallography, revealing its ability to bind metal centres.
Keywords
Supramolecular Chemistry / Dicompartimental Schiff bases / Hydrogen bonds / Manganese
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