EventsThe 14th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-14-00444
This submission belongs to the session a. General Organic Synthesis of the event The 14th International Electronic Conference on Synthetic Organic Chemistry
Published date
30 Oct, 2010
Citation
Mohammad G. Dekamin, Seyyedeh Zahra Ghoreishi, Rahmatollah Rahimi, Mild Oxidation of Benzhydrol by t-Butyl Hydroproxide in the Presence of Silica Supported Iron Porphyrin as a Heterogeneous Catalyst, in Proceedings of The 14th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2010, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-14-00444
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Mild Oxidation of Benzhydrol by t-Butyl Hydroproxide in the Presence of Silica Supported Iron Porphyrin as a Heterogeneous Catalyst

Mohammad G. Dekamin 1
Seyyedeh Zahra Ghoreishi 1
Rahmatollah Rahimi 1
1. Department of Chemistry, Iran University of Science and Technology, Narmak, Tehran 16846-13114, Iran
Abstract
In this study, immobilized Iron (III) complex of meso-tetrakis(p-chlorophenyl) porphyrin [FeIII(TClPP)] on modified silica gel by 3-aminopropyl group has been used as a heterogeneous catalysts for oxidation of benzhydrol by t-butyl hydroproxide (TBH). The reaction was performed at room temperature to afford benzophenone in high yields and short reaction time. Furthermore, the catalyst can be reused for at least 3 reaction cycles without significant lose of its activity.
Keywords
Silica Supported Iron Porphyrin
Oxidation
Heterogeneous Catalyst
Green Chemistry
t-Butyl Hydroproxide (TBH)
Benzhydrol.
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