This submission belongs to the session a. General Organic Synthesis of the event The 14th International Electronic Conference on Synthetic Organic Chemistry
Published date
27 Oct, 2010
Citation
Santiago de la Moya Cerero, Beatriz Lora Maroto, T. de las Casas Engel, E. M. Márquez Sánchez-Carnerero, Different influence of polyoxygenation on the catalytic activity of amido vs. amino isoborneols, in Proceedings of The 14th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2010, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-14-00449
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Different influence of polyoxygenation on the catalytic activity of amido vs. amino isoborneols
Santiago de la Moya Cerero 1
Beatriz Lora Maroto 1
T. de las Casas Engel 1
E. M. Márquez Sánchez-Carnerero 1
1. Dpto. de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Spain.
Abstract
A new series of polyoxygenated amido isoborneols has been synthesized and tested on the enantioselective addition of diethylzinc to benzaldehyde and the results compared to a series of related amino isoborneols. The observed different behavior has been explained on the basis of catalytic quelates previously proposed by us
Keywords
SYNTHESIS OF AROMATIC (PER-O-ACETYL-b-LACTOSYL)-THIOSEMICARBAZONES
SYNTHESIS OF SOME (HEPTA-O-ACETYL-b-LACTOSYL)THIOSEMICARBAZONES CONTAINING BENZENE RING