Events The 14th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 14th International Electronic Conference on Synthetic Organic Chemistry

Published date

30 Oct, 2010

Citation

Marcello Tiecco, Lorenzo Testaferri, Caterina Tidei, Gianni Pintus, Alessio Casagrande, Benedetta Battistelli, Claudio Santi, Zinc-Mediated Synthesis of Vinyl Selenide and GPx-like activity, in Proceedings of The 14th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2010, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-14-00454

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Zinc-Mediated Synthesis of Vinyl Selenide and GPx-like activity

Marcello Tiecco ¹

Lorenzo Testaferri ¹

Caterina Tidei ¹

Gianni Pintus ¹

Alessio Casagrande ¹

Benedetta Battistelli ¹

Claudio Santi ¹

1. Dipartimento di Chimica e Tecnologia del Farmaco Università di Perugia. Viadel Liceo 1 – Perugia – ITALY

Abstract

Phenyl selenol and the zinc-selenolate PhSeZnCl can be conveniently employed for the stereospecific and stereoselective synthesis of vinyl selenides. These reactions occur with moderate to high yields and can be accomplished in eco-compatible conditions using a biphasic acidic system or directly an aqueous suspension.

Keywords

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