EventsMOL2NET'17, Conference on Molecular, Biomed., Comput. & Network Science and Engineering, 3rd ed.
Event submissions
Published
with-doi10.3390/mol2net-03-04631
This submission belongs to the session 02. CHEMBIOMOL-03: Chem. Biol. & Med. Chem. Workshop, Rostock, Germany-Bilbao, Spain-Galveston, Texas, USA, 2017 of the event MOL2NET'17, Conference on Molecular, Biomed., Comput. & Network Science and Engineering, 3rd ed.
Published date
21 Oct, 2017
Citation
Antoine Simonneau, Franck Le Bideau, Jean-Hugues Mirebeau, Gérard Jaouen, Jérôme Marrot, Comments on Tetracarbonyl(pyrrolylimine) Complexes of Rhenium, in Proceedings of MOL2NET'17, Conference on Molecular, Biomed., Comput. & Network Science and Engineering, 3rd ed., 15 January–15 December 2017, MDPI: Basel, Switzerland, doi: 10.3390/mol2net-03-04631
Share
Email
Facebook
Twitter
LinkedIn

Comments on Tetracarbonyl(pyrrolylimine) Complexes of Rhenium

Antoine Simonneau 1
Franck Le Bideau 2
Jean-Hugues Mirebeau 3
Jérôme Marrot 4
Gérard Jaouen 3
1. Laboratoire de Chimie de Coordination du CNRS, UPR 8241, 31077 Toulouse cedex 4, France
2. BioCIS, Université Paris-Sud, CNRS, Université Paris-Saclay, 92290, Châtenay-Malabry, France
3. IPCM,UMR 8232, Université Paris 06, CNRS, F-75005, Paris, France
4. Institut Lavoisier de Versailles, Université de Versailles-Saint-Quentin-en-Yvelines, 78035 Versailles, France
Abstract

The synthesis of tetracarbonyl (pyrrolylimine) complexes of rhenium bearing chirality on the pyrrolyl ligands was reported. The reactivity of these compounds towards the substitution of one carbonyl ligand with triphenyl phosphine, tricyclohexyl phosphine and trimethyl phosphite was studied. The rhenium becoming a stereogenic center in that transformation, the resulting tricarbonyl species were obtained as mixtures of diastereomers, with diastereomeric excesses varying from 8 to 84%, according to the reaction conditions and the relative steric hindrances of the pyrrolylimine and the organophosphorus ligands.

Keywords
Tetracarbonyl(pyrrolylimine) Complexes
Rhenium
Synthesis
Poster
MOL2NET-2017-Simonneau.pdf
MOL2NET-2017-Simonneau.pdf
Physico-chemical and electrochemical properties of nanoparticulate NiO/C composites for high performance lithium and sodium ion battery anodes.
Direct spectrophotometric method to determine cell density of Isochrysis galbana in serial batch cultures from a larger scale fed-batch culture in exponential phase