Sonochemical synthesis of fabrication nano porous metal-organic framework base on tetrakis(4-carboxyphenyl) porphyrin (TCPP) linker

Crystal engineering, the design and synthesis of supramolecular metal-organic frameworks is frontier field in research, not only for their variety of architectures and interesting molecular topologies but also because of their potential applications in zeolite-like catalysts, host-guest chemistry, gas storage, ion exchange, molecular recognition, photonic materials and magnetic. High quality crystals of metal-organic coordination compounds, such as those suitable for single-crystal X-ray diffraction measurements, can usually be obtained by a variety of approaches using wet solution chemistry solvothermal methods [1]. High-energy ultrasound irradiation has been used for the synthesis of a zinc(II) MOF, Zn₂(Zn_TCPP)₃H₂O.2DMF (1), (TCPP) = tetrakis (4-carboxyphenyl) porphyrin in nano scale [2-3]. The nano-structure was characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRPD), FTIR and elemental analyses. The utilization of high intensity ultrasound has found as a facile, environmentally friendly, and versatile synthetic tool for the coordination compounds [4-5].

  Refrences

[1] Hanifehpour.Y, Safarifard.V, Morsali.A, Mirtamizdoust.B, Woo Joo.S, Hanifehpour.Y, Ultrasonics Sonochemistry . 31(2016) 201-205.

[2] EunYoung. Choi, Curtis A. Wray, Chunhua Hu ,Wonyoung Choe. CrystEngComm. 11(2009)553-555.

[3] ArrayDuong Duc La, Hoai Phuong Nguyen Thi, Yong Shin Kim, Anushri Rananaware, Sheshanath V. آ Bhosale , Applied Surface Science . 424(2017) 145-150.

[4]آ  Choi.E, Wary.C,آ  Hu.C, Choe.W, CrystEngComm. 11(2009)553-555.

[5] Rahimi.R, Shariatinia.S, Zargari.S, Yaghobi Berijani.M, Ghaffarinejad.A, Sadat Shojaie.Z, RSC advances. 5(2015) 46624-46631.