Event submissions
Published
This submission belongs to the session A. General Organic Synthesis of the event The 21st International Electronic Conference on Synthetic Organic Chemistry
Published date
03 Nov, 2017
Citation
Thies Thiemann, Abdullah Al-Hemyari, Muna Bufaroosha, Investigation of the Appel reaction with bromotrichloromethane-triphenylphosphine (CBrCl3/PPh3), in Proceedings of The 21st International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2017, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-21-04730
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Investigation of the Appel reaction with bromotrichloromethane-triphenylphosphine (CBrCl3/PPh3)
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Abdullah Al-Hemyari 1
Muna Bufaroosha 1
Thies Thiemann 2
1. Department of Chemistry, UAE University
2. Department of Chemistry, United Arab Emirates University
Abstract
The Appel reaction of an alcohol with CCl4/PPh3 and with CBr4/PPh3 produce alkyl chlorides and alkyl bromides, respectively. It was found that in the case of using CBrCl3-PPh3, a mixture of alkyl chlorides and alkyl bromides are formed. Dichloromethane (CH2Cl2) and acetonitrile (CH3CN) were used as solvents, where the reaction was found to be solvent-dependent.
Keywords
Appel reaction
bromotrichloromethane
alkyl halide
Manuscript
Investigation of the Appel reaction with bromotrichloromethane - PPh3.pdf
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