Events The 21st International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session D. Polymer and Supramolecular Chemistry of the event The 21st International Electronic Conference on Synthetic Organic Chemistry

Published date

03 Nov, 2017

Citation

María J. Romero, Sandra Fernández-Fariña, Luis M. González-Barcia, Rosa Pedrido, Ana M. González-Noya, Marcelino Maneiro, Synthesis of two asymmetric half-salen imine-type ligands as precursors of polynuclear metal complexes, in Proceedings of The 21st International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2017, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-21-04752

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**Synthesis of two asymmetric half-salen imine-type ligands as precursors of polynuclear metal complexes**

María J. Romero ¹

Sandra Fernández-Fariña ¹

Luis M. González-Barcia ¹

Rosa Pedrido ¹

Ana M. González-Noya ¹

Marcelino Maneiro ²

1. Departamento de Química Inorgánica, Facultade de Química, Campus Vida, Universidade de Santiago de Compostela, Santiago de Compostela, 15782, Spain

2. Departamento de Química Inorgánica, Facultade de Ciencias, Universidade de Santiago de Compostela, Lugo, 27002, Spain

Abstract

Herein we report the synthesis and characterization of two asymmetric [NNO] tridentate imine ligands (H₂L¹ and H₂L²) functionalized with two hydroxyl groups and a bulky dansyl moieity. The existence of two hydroxyl substituents able to form bridges between metal ions make both molecules suitable as precursors of metallosupramolecular polynuclear species.

Keywords

Imine-type ligands

dansyl fluorophore

polynuclear complexes

Manuscript

Revised manuscript_ECSOC21_María J Romero.pdf

Poster

ECSOC21-Maria J Romero_presentation.pdf

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