EventsThe 21st International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-21-04771
This submission belongs to the session F. Ionic Liquids of the event The 21st International Electronic Conference on Synthetic Organic Chemistry
Published date
03 Nov, 2017
Citation
Nguyen Dinh Thanh, Le The Duan, Nguyen Thi Minh Nguyet, Le Thi Hoai, Nguyen Thi Thu Ha, STUDY ON REACTION OF SUBSTITUTED 4-METHYLQUINOLIN-2(1H)-ONES WITH SODIUM AZIDE, in Proceedings of The 21st International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2017, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-21-04771
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STUDY ON REACTION OF SUBSTITUTED 4-METHYLQUINOLIN-2(1H)-ONES WITH SODIUM AZIDE

Le The Duan 1
Nguyen Dinh Thanh 2
Nguyen Thi Minh Nguyet 2
Le Thi Hoai 2
Nguyen Thi Thu Ha 2
1. High School for Gifted Students, VNU University of Science (Hanoi, Vietnam)
2. Faculty of Chemistry, VNU Hanoi University of Science, 19 Le Thanh Tong, Hanoi (Vietnam)
Abstract

Reaction of different substituted 2-chloro-4-methylquinolines with sodium azide changed the direction to substituted tetrazolo[1,5-a]quinolines instead corresponding 2-azido-4-methylquinolines. Required 2-chloro-derivatives were obtained from substituted 4-methylquinolin-2(1H)-ones, which were synthesized by ring closing corresponding (un)substituted acetoacetanildes in the presence of ionic liquid [Bmim]OH. The structures of obtained compounds have been confirmed by using spectroscopic methods (IR, NMR and MS).

Keywords
Knorr synthesis
4-methylquinolin-2(1H)-ones
ionic liquid
sodium azido.
Manuscript
submission sciforum-014572-nguyendinhthanh.pdf
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