EventsThe 21st International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-21-04807
This submission belongs to the session A. General Organic Synthesis of the event The 21st International Electronic Conference on Synthetic Organic Chemistry
Published date
03 Nov, 2017
Citation
Victor V. Dotsenko, Andrey S. Levashov, Dmitriy S. Buriy, Inna V. Aksenova, Nikolay A. Aksenov, Valeriy V. Konshin, Oppenauer-type synthesis of α, β-acetylenic ketones from tetra(phenylethynyl)tin and aromatic aldehydes, in Proceedings of The 21st International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2017, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-21-04807
Share
Email
Facebook
Twitter
LinkedIn

Oppenauer-type synthesis of α, β-acetylenic ketones from tetra(phenylethynyl)tin and aromatic aldehydes

Andrey S. Levashov 1
Dmitriy S. Buriy 1
Valeriy V. Konshin 1
Victor V. Dotsenko 1,2,3
Inna V. Aksenova 3
Nikolay A. Aksenov 3
1. Kuban State University, 149 Stavropolskaya Str., Krasnodar 350040, Russian Federation
2. ChemEx Lab, Vladimir Dal’ Lugansk National University, Lugansk, 91034 Russia.
3. North-Caucasus Federal University, 1 Pushkina St., 355009 Stavropol, Russian Federation
Abstract

Tetra(phenylethynyl)tin reacts with aromatic aldehydes in the presence of a Lewis acid followed by the Oppenauer-type in situ oxidation of propargyl alcohols to give acetylenic ketones in a very good yield.

Keywords
Organotin compounds
tetraalkynylstannane
Oppenauer oxidation
α
β-acetylenic ketones
Manuscript
ECOSC 21 2017 Levashov Oppenauer acetylenic ketones.pdf
Preparation and Structural Assessment of Cocrystal Solvates and Cocrystal Salts of 1,3,5-Triazine-2,4,6-triamine with alpha-Hydroxycarboxylic Acids
Forced degradation studies on Naratriptan HCL by High Performance Liquid Chromatography.