Events The 14th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 14th International Electronic Conference on Synthetic Organic Chemistry

Published date

05 Nov, 2010

Citation

Mansoor Anbia, Rahmatollah Rahimi, Nafiseh RahmaniKhalili, Efficient Catalytic Oxidation of Cyclohexane by Metalloporphyrins Encapsulated Mesoporous MCM-48, in Proceedings of The 14th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2010, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-14-00496

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Efficient Catalytic Oxidation of Cyclohexane by Metalloporphyrins Encapsulated Mesoporous MCM-48

Mansoor Anbia ¹

Rahmatollah Rahimi ¹

Nafiseh RahmaniKhalili ¹

1. Department of chemistry, Iran University Of Science & Technology, Tehran 16846-13114, Iran

Abstract

Catalytic oxidation of cyclohexane by two metalloporphyrins {manganese and iron 5, 10, 15, 20-meso-tetrakis-(p-chlorophenyl) porhyrin}immobilized in mesoporous MCM-48 with TBHP in acetonitril was investigated. It was found that immobilization significantly enhances catalytic activity as compared to the homogenous system.

Keywords

cyclohexane oxidation

metalloporphyrins

MCM-48

Synthesis and Biological Activity of Some New Heterocyclic Compounds