EventsMOL2NET'17, Conference on Molecular, Biomed., Comput. & Network Science and Engineering, 3rd ed.
Event submissions
Published
with-doi10.3390/mol2net-03-05091
This submission belongs to the session 01. CHEMBIOINFO-03: Chem-Bioinformatics Congress Cambridge, UK-Chapel Hill and Richmond, USA, 2017 of the event MOL2NET'17, Conference on Molecular, Biomed., Comput. & Network Science and Engineering, 3rd ed.
Published date
19 Dec, 2017
Citation
Esther Domínguez, Garazi Urgoitia, María Teresa Herrero, Raul Sanmartin, Efficient preparation of carboxylic acids from alkynes, in Proceedings of MOL2NET'17, Conference on Molecular, Biomed., Comput. & Network Science and Engineering, 3rd ed., 15 January–15 December 2017, MDPI: Basel, Switzerland, doi: 10.3390/mol2net-03-05091
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Efficient preparation of carboxylic acids from alkynes

Esther Domínguez 1
Garazi Urgoitia 1
María Teresa Herrero 1
Raul Sanmartin 1
1. University of Basque Country
Abstract

The preparation of carboxylic acids from arylacetylenes has traditionally been carried out by ozonolysis or other harmful oxidants, alone or in presence of some metal catalysts. In spite of the safety, availability and environmental benignity of molecular oxygen, the selective cleavage of unsaturated hydrocarbons mediated by the latter oxidant has been rarely reported. Herein we wish to present the efficient preparation of carboxylic acid derivatives  from alkynes employing molecular oxygen as the only oxidant and in the presence of a Ni(II) salt and 1,2,4-triazole ligands

Keywords
alkenes
carboxylic acids
fragmentation
nickel
oxidation
aerobic
Poster
mol2net-03_Akyne cleavage.pdf
mol2net-03_Akyne cleavage.pdf
Diyne formation from alkynes in the presence of palladium pincer complexes
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