Events MOL2NET'17, Conference on Molecular, Biomed., Comput. & Network Science and Engineering, 3rd ed.

Event submissions

Published

This submission belongs to the session 02. CHEMBIOMOL-03: Chem. Biol. & Med. Chem. Workshop, Rostock, Germany-Bilbao, Spain-Galveston, Texas, USA, 2017 of the event MOL2NET'17, Conference on Molecular, Biomed., Comput. & Network Science and Engineering, 3rd ed.

Published date

20 Dec, 2017

Citation

Galder Llorente, Aimar García, Esther Domínguez, Garazi Urgoitia, Iratxe Astarloa, María Teresa Herrero, Nerea Conde, Raul Sanmartin, A more efficient catalyst for the cycloisomerization of alkynoic acids , in Proceedings of MOL2NET'17, Conference on Molecular, Biomed., Comput. & Network Science and Engineering, 3rd ed., 15 January–15 December 2017, MDPI: Basel, Switzerland, doi: 10.3390/mol2net-03-05104

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A more efficient catalyst for the cycloisomerization of alkynoic acids

Galder Llorente ¹

Aimar García ¹

Esther Domínguez ¹

Garazi Urgoitia ¹

Iratxe Astarloa ¹

María Teresa Herrero ¹

Nerea Conde ¹

Raul Sanmartin ¹

1. University of Basque Country

Abstract

A number of terminal and internal alkynoic acids with different substitution patterns have been efficiently cycloisomerized to the corresponding exocyclic enol lactones in the presence of low amounts of a non-symmetric NNC palladium complex and a catalytic amount of triethylamine.

Keywords

alkynoic acid

cycloisomerization

palladium

pincer

Poster

mol2net 2017 cycloisomerization.pdf

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