Events The 22nd International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session C. General Organic Synthesis of the event The 22nd International Electronic Conference on Synthetic Organic Chemistry

Published date

14 Nov, 2018

Citation

Victor V. Dotsenko, Arif Ismiev, Gunay Zakhid Mamedova, Nikolai A. Aksenov, Inna V. Aksenova, Abel Mamedali Magerramov, A new approach to the synthesis of functionalized bicyclo[3.2.1]octanes, in Proceedings of The 22nd International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2018, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-22-05794

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A new approach to the synthesis of functionalized bicyclo[3.2.1]octanes

Arif Ismiev ¹

Gunay Zakhid Mamedova ¹

Victor V. Dotsenko ^2,3,4

Nikolai A. Aksenov ⁴

Inna V. Aksenova ⁴

Abel Mamedali Magerramov ¹

1. Baku State University, 23 Academic Zahid Khalilov str, AZ 1148 Baku, Republic of Azerbaijan

2. Kuban State University, 149 Stavropolskaya Str., Krasnodar 350040, Russian Federation

3. ChemEx Lab, Vladimir Dal’ Lugansk National University, Lugansk, 91034 Russia.

4. North-Caucasus Federal University, 1 Pushkina St., 355009 Stavropol, Russian Federation

Abstract

The reaction of furfural with secondary amines and isopropyl cyanoacetate leads to the formation of the previously unknown diisopropyl 8-(dialkylamino)-2,4-dicyano-3-(2-furyl)-6-oxobicyclo[3.2.1]octane-2,4-dicarboxylates. The tructure of the products was confirmed by NMR and X-ray analysis.

Keywords

furfural

isopropyl cyanoacetate

Stenhouse salt

Nazarov reaction

carbocyclization

bicyclo[3.2.1]octane

Manuscript

ecsoc22 arif.pdf

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