EventsThe 23rd International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-23-06494
This submission belongs to the session A. General Organic Synthesis of the event The 23rd International Electronic Conference on Synthetic Organic Chemistry
Published date
14 Nov, 2019
Citation
Marcos Rúa-Sueiro, Paula Munin-Cruz, Francisco Reigosa, José M. Vila, M. Teresa Pereira, Synthesis and characterization of novel thiosemicarbazone palladacycles, in Proceedings of The 23rd International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2019, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-23-06494
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Synthesis and characterization of novel thiosemicarbazone palladacycles

Marcos Rúa-Sueiro 1
Paula Munin-Cruz 1
Francisco Reigosa 1
José M. Vila 1
M. Teresa Pereira 1
1. Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiago de Compostela, Santiago de Compostela
Abstract

Since the appearance of the term palladacycle, as coined by Trofimenko[1], one of the most salient group of such compounds is the thiosemicarbazone class.

Herein, the synthesis and characterization of several palladium cyclometallated compounds with thiosemicarbazone ligands is discussed. The ligands were synthesized by treatment of a ketone with four different thiosemicarbazides in acidified aqueous solution; after which there were conveniently treated with a palladium salt thus yielding the corresponding palladacycle. All show a tetranuclear structure with [C, N, S] coordination of the ligands to the metal centers.

[1] S. Trofimenko, Inorg. Chem., 1973, 12, 1215.

Keywords
Cyclometallated
thiosemicarbazones
palladium
Manuscript
23 ECSOC Marcos Rúa Sueiro.pdf
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