Events The 15th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session c. Microwave Assisted Synthesis of the event The 15th International Electronic Conference on Synthetic Organic Chemistry

Published date

30 Oct, 2011

Citation

M. Pilar Vázquez-Tato, Xesús Feás, Sandra Labandeira-Peteiro, Julio A Seijas, Synthesis of triols with C₃ symmetry by ring opening of tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione with nucleophiles, in Proceedings of The 15th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2011, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-15-00690

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Synthesis of triols with C₃ symmetry by ring opening of tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione with nucleophiles

M. Pilar Vázquez-Tato ¹

Xesús Feás ¹

Sandra Labandeira-Peteiro ¹

Julio A Seijas ¹

1. Department of Organic Chemistry. Facultade de Ciencias. Universidade de Santiago de Compostela. Aptdo. 280. 27080-Lugo. Spain

Abstract

The reaction of tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione with phenol or N-methylaniline promoted by microwave heating, under solventless conditions, led to the opening of the oxirane ring through the less hindered carbon, leading to tripodal triols with C₃ symmetry in good yields.

Keywords

1,3,5-triazinane-2,4,6-trione

microwave

oxirane

triol

Click reactions in the synthesis of tripodal 1H-1,2,3-triazol derivatives of 1,3,5-triazinane-2,4,6-trione

Structural studies of phenylhydrazine integration in carbohydrate derivatives

Synthesis of triols with C3 symmetry by ring opening of tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione with nucleophiles

Synthesis of triols with C₃ symmetry by ring opening of tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione with nucleophiles