Event submissions
Published
This submission belongs to the session C. Crystal Engineering of the event The 2nd International Online Conference on Crystals
Published date
06 Nov, 2020
Citation
Marcos Rúa-Sueiro, Paula Munin-Cruz, Francisco Reigosa, José M. Vila, Juan M. Ortigueira, Synthesis and X-ray diffraction study of thiosemicarbazone palladacycles with dppm, in Proceedings of The 2nd International Online Conference on Crystals, 10 November–20 November 2020, MDPI: Basel, Switzerland, doi: 10.3390/IOCC_2020-07352
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Synthesis and X-ray diffraction study of thiosemicarbazone palladacycles with dppm
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Marcos Rúa-Sueiro 1
Paula Munin-Cruz 1
Francisco Reigosa 1
José M. Vila 1
Juan M. Ortigueira 1
1. Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiago de Compostela, Santiago de Compostela
Abstract
Cyclometallated compounds have been extensively studied, in particular those with palladium and platinum. This is because of their possible applications in medicinal chemistry, as anticancer or antimicrobial agents; in some cases with similar results as cisplatin, carboplatin or oxaliplatin. Also remarkable is their use as homogeneous catalysts, for example, in cross coupling reactions such as Suzuki-Miyaura or Mizoroki-Heck.
Herein we report the synthesis of different thiosemicarbazone ligands, which will be reacted with a palladium or platinum salt, to give the corresponding cyclometallated compounds; their reactivity with bis(diphenylphosphino)methane (dppm) will be studied.
Characterization has been carried by elemental analysis, IR spectroscopy, 1H and 31P NMR spectroscopy. Also, 1c has been studied by X-ray diffraction.
Keywords
cyclometallation
thiosemicarbazone
palladium
platinum
X-ray diffraction
Manuscript
sciforum-038668 。pdf.pdf
Poster
sciforum-038668 .pdf
Attainment of Pentagonal-Bipyramidal LnIII Complexes from a planar pentadentate ligand
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