Events The 24th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session A. General Organic Synthesis of the event The 24th International Electronic Conference on Synthetic Organic Chemistry

Published date

14 Nov, 2020

Citation

Marcos Rúa-Sueiro, Paula Munin-Cruz, Francisco Reigosa, José M. Vila, M. Teresa Pereira, Juan M. Ortigueira, Synthesis of mono- and dinuclear cyclometallated compounds with palladium and platinum, in Proceedings of The 24th International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2020, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-24-08299

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Synthesis of mono- and dinuclear cyclometallated compounds with palladium and platinum

Marcos Rúa-Sueiro ¹

Paula Munin-Cruz ¹

Francisco Reigosa ¹

José M. Vila ¹

M. Teresa Pereira ¹

Juan M. Ortigueira ¹

1. Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiago de Compostela, Santiago de Compostela

Abstract

Cyclometallated compounds, particularly with palladium and platinum, have been extensively studied over the past years in part due to their applications as catalysts in cross-coupling reactions. They are also useful in medicinal chemistry, and quite a large number have luminescent properties.

Herein, the synthesis and characterization of novel palladium cyclometallated compounds and a study of their reactivity with a diphosphine ligand is discussed. Mono- and dinuclear compounds were prepared depending on phosphine ligand coordination.

Characterization has been carried by IR spectroscopy, ¹H and ³¹P NMR spectroscopy.

Keywords

cyclometallation

palladium

platinum

thiosemicarbazone

diphosphine

Manuscript

sciforum-038664.pdf

Study of ADMET Descriptors of Novel Chlorinated N-Arylcinnamamides

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