EventsThe 24th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-24-08320
This submission belongs to the session A. General Organic Synthesis of the event The 24th International Electronic Conference on Synthetic Organic Chemistry
Published date
14 Nov, 2020
Citation
Sara Bermudez, Raquel Diz-Gil, Paula Munín-Cruz, Marcos Rúa-Sueiro, Juan M. Ortigueira, José M. Vila, Preparation of novel complexes bearing diphosphine (dppm) derived from thiosemicarbazone palladacycles, in Proceedings of The 24th International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2020, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-24-08320
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Preparation of novel complexes bearing diphosphine (dppm) derived from thiosemicarbazone palladacycles

Sara Bermudez 1
Raquel Diz-Gil 1
Paula Munín-Cruz 1
Marcos Rúa-Sueiro 1
Juan M. Ortigueira 1
José M. Vila 1
1. Department of Inorganic Chemistry, University of Santiago de Compostela, Spain
Abstract

The synthesis of palladium cyclometallated compounds with thiosemicarbazone ligands is described,as well as their reactivity with bidentate phosphine ligands. The synthesis of the ligands is carried out by a condensation reaction between a ketone and a thiosemicarbazide. Subsequently, metallation proceeds, and the resulting product is reacted with the bis(diphenylphosphino)methane (dppm) using the appropriate conditions to obtain the compound with phosphine in a monodentate coordination mode.

Keywords
thiosemicarbazone
palladium
organometallic
Manuscript
sciforum-039206.pdf
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