EventsThe 24th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-24-08321
This submission belongs to the session A. General Organic Synthesis of the event The 24th International Electronic Conference on Synthetic Organic Chemistry
Published date
14 Nov, 2020
Citation
Paula Munín-Cruz, Marcos Rúa-Sueiro, Juan Manuel Ortigueira, José Manuel Vila, Synthesis of novel bisiminophosphorane palladacycles with miscellaneous bidentate chelating ligands, in Proceedings of The 24th International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2020, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-24-08321
Share
Email
Facebook
Twitter
LinkedIn

Synthesis of novel bisiminophosphorane palladacycles with miscellaneous bidentate chelating ligands

Paula Munín-Cruz 1
Marcos Rúa-Sueiro 2
Juan Manuel Ortigueira 2
José Manuel Vila 2
1. Department of Inorganic Chemistry, University of Santiago de Compostela, Spain
2. Department of Inorganic Chemistry, University of Santiago de Compostela
Abstract

Bisiminophosphorane palladacycles were synthesized efficiently through the cyclometallation process providing tetranuclear palladium species with macrocycle-type structures. These ensuing compounds were reacted with different bidentate ligands in a 1:4 ratio. The results showed that only bimetallic complexes with two chelating ligands were obtained. This puts forward that the chelate effect predominates in this process over the macrocycle effect.

Keywords
Palladacycles
Bisiminophosphoranes
Chelation
Manuscript
GeneralOrganicSynthesis_8321_Synthesis_of_novel_bisiminopho_done.pdf
Preparation of novel complexes bearing diphosphine (dppm) derived from thiosemicarbazone palladacycles
Preparation and crystal structure of metallated 2,4,6-trimethylaniline imines