EventsThe 24th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-24-08338
This submission belongs to the session F. Ionic Liquids of the event The 24th International Electronic Conference on Synthetic Organic Chemistry
Published date
14 Nov, 2020
Citation
Claudia Della Rosa, Claudia G. Adam, Effect on Cycloaddition Reactions of Aqueous Micellar Systems formed by Amphiphilic Imidazolium Ionic Liquids, in Proceedings of The 24th International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2020, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-24-08338
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Effect on Cycloaddition Reactions of Aqueous Micellar Systems formed by Amphiphilic Imidazolium Ionic Liquids

Claudia Della Rosa 1
Claudia G. Adam 1
1. IQAL (UNL-CONICET), Laboratorio Fisicoquímica Orgánica, Facultad de Ingeniería Química, Universidad Nacional del Litoral
Abstract

The micellar effect on a Diels-Alder reaction (DA) was analyzed taking advantage of the property presented by Ionic Liquids (ILs) based on 1-alkyl-3-methylimidazolium cations by having amphiphilic character when the alkyl group is a long hydrocarbon chain -12 carbon atoms [C12mim]-. These ILs can act as surfactants forming micelles in aqueous solution.

The reactive system studied consists of nitrofuran and isoprene which allows obtaining benzofuran through green synthetic strategie.

These “new microheterogeneous systems” would allow a better solubilization of non-polar substrates and to adopt reaction conditions softer than the traditional thermal.

Keywords
Amphiphilic Ionic Liquids
Micelles
Diels-Alder
Manuscript
IonicLiquids_8338_Effect_on_Cycloaddition_Reacti_original.pdf
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