EventsThe 24th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-24-08359
This submission belongs to the session A. General Organic Synthesis of the event The 24th International Electronic Conference on Synthetic Organic Chemistry
Published date
14 Nov, 2020
Citation
Hossein Ghafuri, Fatemeh Ganjali, Peyman Hanifehnejad, Cu.BTC MOF as a novel and efficient catalyst for the synthesis of 1, 8-dioxo-octa-hydro xanthene, in Proceedings of The 24th International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2020, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-24-08359
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Cu.BTC MOF as a novel and efficient catalyst for the synthesis of 1, 8-dioxo-octa-hydro xanthene

Hossein Ghafuri 1
Fatemeh Ganjali 2
Peyman Hanifehnejad 3
1. Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran16846-13114, Iran, Iran
2. Department of Chemistry, Iran University of Science and Technology, Tehran16846-13114, Iran
3. Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran16846-13114, Iran
Abstract

A copper-based metal-organic framework with 1, 3, 5-tricarboxylic acid linkers was prepared through a facile hydrothermal method. This MOF has not been used in organic reactions widely. Cu.BTC was employed as an affordable, competent heterogeneous catalyst in 1, 8-dioxo-octa-hydro xanthene synthesis. Additionally, the structure, morphology, and porosity of this catalyst were considered. Various techniques such as FE-SEM, BET, EDS, FT-IR, and XRD applied to this aim. As a result, Cu.BTC had a mesoporous structure, an excellent specific surface area, and high purity. Some privileges of using this heterogeneous catalyst in 1, 8-dioxo-octa-hydro xanthene synthesis are mild condition, increased activity, ease in separation, and reusability. Also, 1, 8-dioxo-octa-hydro xanthene was obtained via simple recrystallization.

Keywords
Cu.BTC MOF
catalyst
1
8-dioxo-octa-hydro xanthene synthesis
xanthene.
Manuscript
GeneralOrganicSynthesis_8359_Cu_BTC_MOF_as_a_novel_and_effi_done.pdf
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