EventsThe 24th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-24-08399
This submission belongs to the session A. General Organic Synthesis of the event The 24th International Electronic Conference on Synthetic Organic Chemistry
Published date
14 Nov, 2020
Citation
Victor V Dotsenko, Anna E. Sinotsko, Nicolai A. Aksenov, The reactions of N,N'-diphenyldithiomalonamide with Michael acceptors, in Proceedings of The 24th International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2020, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-24-08399
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The reactions of N,N'-diphenyldithiomalonamide with Michael acceptors

Anna E. Sinotsko 1
Victor V Dotsenko 2,3,4
Nicolai A. Aksenov 4
1. Kuban State University
2. Department of Organic Chemistry and Technologies, Kuban State University, 149 Stavropolskaya Str., 350040 Krasnodar, Russia
3. ChemEx Lab, Vladimir Dal’ Lugansk National University
4. North Caucasus Federal University
Abstract

N,N'-diphenyldithiomalonamide (dithiomalondianilide) smoothly reacts with various Michael acceptors to give either stable Michael adducts or products of their further heterocyclization. The structure of the products was confirmed by 2D NMR experiments and X-ray data. The mechanisms of the reactions are discussed.

Keywords
dithiomalondianilide
heterocyclization
2-cyanoacrylates
Meldrum’s acid
Michael adducts
Manuscript
GeneralOrganicSynthesis_8399_The_reactions_of_N_N_diphenyl_original-done.pdf
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