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Benzylic Newman-Kwart rearrangement triggered by Phosphanes
Published:
28 November 2008
by MDPI
in The 12th International Electronic Conference on Synthetic Organic Chemistry
session General Organic Synthesis
Abstract: A Staudinger imination reaction of tertiary phosphanes with O-(azidobenzyl)thioncarbamates, bearing the azido function at ortho or para position, promotes a rare benzylic Newman-Kwart rearrangement.
Keywords: n/a