SYNTHESIS OF 3-SUBSTITUTED 1H-PHOSPHOLANOXIDES BY THE INTERACTION OF ALUMOLANES WITH PBr3/H2O

Alevtina Makhamatkhanova; Tatyana Tyumkina

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SYNTHESIS OF 3-SUBSTITUTED 1H-PHOSPHOLANOXIDES BY THE INTERACTION OF ALUMOLANES WITH PBr3/H2O

Alevtina Makhamatkhanova

^{*

1},

Tatyana Viktorovna Tyumkina

¹ Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences
² Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences

Academic Editor: Julio A. Seijas

Published: 15 November 2023 by MDPI in The 27th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-27-16045 (registering DOI)

Abstract:

We have recently developed a method for the synthesis of 3R-substituted and norbornane-annelated 1H-phospholanoxides based on the reaction of replacement of aluminum atoms in alumolane with phosphorus atoms by phosphorus trichloride. . In development of our research, we have established that the use of PBr3 as a phosphorus reagent also successfully allows us to obtain target 1H-phospholanoxides.

Keywords: phospholanes; alumolane; cycloalumination; phosphorus trichloride.

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Alevtina Makhamatkhanova

Tatyana Tyumkina