Enantioselective Palladium Catalyzed Allylic Substitution with New Multichiral Centers Monophosphine Ligands

Jean Brunel; Martin Smith; Sebastien Reymond

doi:10.3390/ecsoc-4-01841

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A Highly Stereoselective Synthesis of Carbamate Protected anti-1,2-Aminoalcohols

Enantioselective Palladium Catalyzed Allylic Substitution with New Multichiral Centers Monophosphine Ligands

Jean Michel Brunel

^*,

Martin Smith

Sebastien Reymond

Published: 11 September 2000 by MDPI in The 4th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-4-01841

Abstract: The synthesis of new multichiral center monophosphine ligands 1-3 was achieved and assessed in the enantioselective palladium catalyzed allylic substitution of 1,3-diphenyl-2-propenyl acetate 4 with enantioselectivities up to 92%

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Jean Brunel

Martin Smith

Sebastien Reymond